Carbon Dioxide Adsorption on MOF-199 Metal-Organic Framework at High Pressure
نویسندگان
چکیده
منابع مشابه
Synthesis and Electrospraying of Nanoscale MOF (Metal Organic Framework) for High-Performance CO2 Adsorption Membrane
We report the sonochemical synthesis of MOF (metal organic framework) nanoparticles of 30-200 nm in size and electrospraying of those particles on electrospun nanofibers to process a MOF-attached nanofibrous membrane. This membrane displayed significant selectivity towards CO2 and capacity of adsorbing with 4000-5000 ppm difference from a mixed gas flow of 1% CO2 and 99% N2. Applying ultrasonic...
متن کاملThe mechanism of carbon dioxide adsorption in an alkylamine-functionalized metal-organic framework.
The mechanism of CO2 adsorption in the amine-functionalized metal-organic framework mmen-Mg2(dobpdc) (dobpdc(4-) = 4,4'-dioxidobiphenyl-3,3'-dicarboxylate; mmen = N,N'-dimethylethylenediamine) was characterized by quantum-chemical calculations. The material was calculated to demonstrate 2:2 amine:CO2 stoichiometry with a higher capacity and weaker CO2 binding energy than for the 2:1 stoichiomet...
متن کاملUnravelling exceptional acetylene and carbon dioxide adsorption within a tetra-amide functionalized metal-organic framework
Understanding the mechanism of gas-sorbent interactions is of fundamental importance for the design of improved gas storage materials. Here we report the binding domains of carbon dioxide and acetylene in a tetra-amide functionalized metal-organic framework, MFM-188, at crystallographic resolution. Although exhibiting moderate porosity, desolvated MFM-188a exhibits exceptionally high carbon dio...
متن کاملSelective sulfur dioxide adsorption on crystal defect sites on an isoreticular metal organic framework series
The widespread emissions of toxic gases from fossil fuel combustion represent major welfare risks. Here we report the improvement of the selective sulfur dioxide capture from flue gas emissions of isoreticular nickel pyrazolate metal organic frameworks through the sequential introduction of missing-linker defects and extra-framework barium cations. The results and feasibility of the defect pore...
متن کاملsorption of methane and carbon dioxide on nano porous zinc carboxylate metal-organic framework
zinc (ⅱ) tricarboxylate (zn-btc) with metal-organic framework (mof) has been synthesized for the first time under solvothermal conditions and has been tested as an adsorbent for methane and carbon dioxide at standard temperature and pressure. the adsorbent was characterized by means of x-ray diffraction(xrd), brunauer-emmet-teller (bet), fourier transform infrared (ft-ir) and scanning electron ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: IOP Conference Series: Materials Science and Engineering
سال: 2019
ISSN: 1757-899X
DOI: 10.1088/1757-899x/557/1/012060